photons accelerate virtually instantly. However, to my understanding (it's been a while), light photons slow down depending on the medium in which they are traveling. For example, we see the light spectrum through a prism because the various forms of light travel through the prism at different speeds. I believe this is called "Light Dispersion." The process of slowing down would be very taxing, in that the time it would take you to accelerate and decelerate without turning into mush would eat up a lot of precious road time.
Nevertheless, as previously stated, 'reversing the thrusters' would be the way to do it.
Traveling by the speed of light is theoretically obsolete. It just is not fast enough to get us 'out there.' Granted, we could cover some ground in our own back yard, but that is about it. For example, our nearest galactic neighbor, Andromeda, whose light travels at a blistering 186,000 miles per second, still takes a grueling 2,900 years to get here.
Quantum teleportation and worm holes are the ticket!