In order to block out IP's (and not MAC's) that means that every administrator pc's will have a static IP, therefore your best choice would probably be spoofing you're IP.
Once inside you can add another IP to the static list and add an exclusion in DHCP (so you can use it at any time).
I'm not 100% sure, however, I believe that according to the hardware installed you can get some problems with IP Spoofing if you and the real client are log in at same time.
I believe Hubs will simply forward all the info according to the IP and will not check the MAC which means you'll get data meant for the real admin and your own data, the same would happen to him.
While Routers will compare the MAC also and shouldn't cause any problems.
However there is no way to get access to the whitelist remotely, you should get access to the network/server first.